No, you need to use Blender, for which there is a complete model that is already rigged. If you use POV-ray, you'll need to model the whole thing yourself.
ETA: There IS a POV-ray tutorial for making high quality replays, but I don't know if you can change the textures shown.
Last edited by JWideman; Feb 22, 2010 at 10:36 PM.
Reason: Added info
Blender is for custom images and animations, which is what I thought you were wanting to do. POV-ray is for replays or screenshots. There's a tutorial.