Honestly, it wouldn't be great. Your cpu and ram bottleneck the hell out of everything, so getting a new GPU wouldn't do anything unless you upgraded your rig or it was something like a 7770 (which isn't bad). Also, 32 bit win7 is pretty bad compared to 64 bit, and if you ever plan to upgrade your rig, (ie 4-8gb of ram and a decent 4-8 core 2x-4x ghz cpu), you will need to reinstall your os to grab 64 bit unless you never plan to upgrade.
Anyway, tl;dr, your cpu and ram also say a lot in framerate of video games, so don't just get a nice gpu and expect it to be perfect, you really should just try to upgrade your rig or something.